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（5''E）-1''-苄基-1'-甲基-5''-[4-（甲硫基）亚苄基]-4'-[4-（甲硫基）苯基]二螺[吲哚啉-3,2'-吡咯烷-3',3''-哌啶]-2,4''-二酮二氯甲烷溶剂合物

(5''E)-1''-Benzyl-1'-methyl-5''-[4-(methyl-sulfan-yl)benzyl-idene]-4'-[4-(methyl-sulfan-yl)phen-yl]dispiro-[indoline-3,2'-pyrrolidine-3',3''-piperidine]-2,4''-dione dichloro-methane solvate.

作者信息

Hou Yongjiang

机构信息

School of Environmental Science and Engineering, Hebei University of Science and Technology. 050018 Shijiazhuang, Hebei province, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 24;66(Pt 1):o244. doi: 10.1107/S1600536809054774.

DOI:10.1107/S1600536809054774
PMID:21580125
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2980017/
Abstract

In the title compound, C(38)H(36)N(3)O(2)S(2)·CH(2)Cl(2), the 2-oxindole ring is almost planar (r.m.s. deviation = 0.032 Å), the pyrrolidine ring adopts a twist conformation and the piperidone ring exists as a chair. Three short C-H⋯O intra-molecular contacts occur. In the crystal, mol-ecules are linked by C-H⋯O and C-H⋯N inter-actions. The dichloro-methane solvent mol-ecule is disordered over two orientations in a 0.765 (11):0.235 (11) ratio.

摘要

在标题化合物C(38)H(36)N(3)O(2)S(2)·CH(2)Cl(2)中，2-氧化吲哚环几乎呈平面状（均方根偏差 = 0.032 Å），吡咯烷环呈扭曲构象，哌啶酮环以椅式存在。存在三个短的C-H⋯O分子内接触。在晶体中，分子通过C-H⋯O和C-H⋯N相互作用相连。二氯甲烷溶剂分子在两种取向上无序排列，比例为0.765 (11):0.235 (11)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11d8/2980017/74b37eff76cf/e-66-0o244-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11d8/2980017/74b37eff76cf/e-66-0o244-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11d8/2980017/74b37eff76cf/e-66-0o244-fig1.jpg

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