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N-（4-氯苯基）-7-氧杂双环-[2.2.1]庚-5-烯-2,3-二甲酰亚胺

N-(4-Chloro-phen-yl)-7-oxabicyclo-[2.2.1]hept-5-ene-2,3-dicarboximide.

作者信息

Li Jian

机构信息

Department of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 20;66(Pt 12):o3238. doi: 10.1107/S1600536810047537.

DOI:10.1107/S1600536810047537
PMID:21589527
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3011550/
Abstract

In the title racemic compound, C(14)H(10)ClNO(3), which contains four stereogenic centres, the cyclo-hexane ring tends towards a boat conformation, while the tetra-hydro-furan and dihydro-furan rings adopt envelope conformations. The dihedral angle between the mean planes of the pyrrolidine-2,5-dione unit and the 4-chloro-phenyl ring is 49.0 (2)°.

摘要

在标题外消旋化合物C(14)H(10)ClNO(3)中，它含有四个手性中心，环己烷环倾向于船式构象，而四氢呋喃环和二氢呋喃环采取信封式构象。吡咯烷-2,5-二酮单元与4-氯苯基环的平均平面之间的二面角为49.0 (2)°。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3a97/3011550/9eeab30218f7/e-66-o3238-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3a97/3011550/9eeab30218f7/e-66-o3238-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3a97/3011550/9eeab30218f7/e-66-o3238-fig1.jpg

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