2-[4,5-双(丁硫基)-1,3-二硫醇-2-亚基]-5-甲基-5H-1,3-二硫并[4,5-c]吡咯-4-甲醛
2-[4,5-Bis(butyl-sulfan-yl)-1,3-dithiol-2-yl-idene]-5-methyl-5H-1,3-dithiolo[4,5-c]pyrrole-4-carbaldehyde.
作者信息
Hou Rui-Bin, Yin Bing-Zhu
机构信息
Key Laboratory of Natural Resources of Changbai Mountain & Functional Molecules (Yanbian University), Ministry of Education, Yanji 133002, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 30;66(Pt 12):o3353. doi: 10.1107/S160053681004910X.
Abstract
In the title compound, C(18)H(23)NOS(6), the dithiol-opyrrole ring is almost planar [r.m.s. deviation = 0.044 (3) Å] and makes a dihedral angle of 25.11 (7)° with the dithiole ring. In the crystal, pairs of neighboring mol-ecules are connected by weak inter-molecular C-H⋯O inter-actions. These dimers are further linked into a chain along [110] by C-H⋯O inter-actions.
摘要
在标题化合物C(18)H(23)NOS(6)中，二硫醇吡咯环几乎是平面的[r.m.s.偏差 = 0.044 (3) Å]，与二硫环形成25.11 (7)°的二面角。在晶体中，相邻分子对通过弱的分子间C-H⋯O相互作用相连。这些二聚体通过C-H⋯O相互作用进一步沿[110]连接成链。
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