• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

2-[4,5-双(丁硫基)-1,3-二硫醇-2-亚基]-5-甲基-5H-1,3-二硫并[4,5-c]吡咯-4-甲醛

2-[4,5-Bis(butyl-sulfan-yl)-1,3-dithiol-2-yl-idene]-5-methyl-5H-1,3-dithiolo[4,5-c]pyrrole-4-carbaldehyde.

作者信息

Hou Rui-Bin, Yin Bing-Zhu

机构信息

Key Laboratory of Natural Resources of Changbai Mountain & Functional Molecules (Yanbian University), Ministry of Education, Yanji 133002, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 30;66(Pt 12):o3353. doi: 10.1107/S160053681004910X.

DOI:10.1107/S160053681004910X
PMID:21589623
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3011525/
Abstract

In the title compound, C(18)H(23)NOS(6), the dithiol-opyrrole ring is almost planar [r.m.s. deviation = 0.044 (3) Å] and makes a dihedral angle of 25.11 (7)° with the dithiole ring. In the crystal, pairs of neighboring mol-ecules are connected by weak inter-molecular C-H⋯O inter-actions. These dimers are further linked into a chain along [110] by C-H⋯O inter-actions.

摘要

在标题化合物C(18)H(23)NOS(6)中，二硫醇吡咯环几乎是平面的[r.m.s.偏差 = 0.044 (3) Å]，与二硫环形成25.11 (7)°的二面角。在晶体中，相邻分子对通过弱的分子间C-H⋯O相互作用相连。这些二聚体通过C-H⋯O相互作用进一步沿[110]连接成链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2e27/3011525/55fdccfeb88e/e-66-o3353-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2e27/3011525/55fdccfeb88e/e-66-o3353-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2e27/3011525/55fdccfeb88e/e-66-o3353-fig1.jpg

相似文献

1
2-[4,5-Bis(butyl-sulfan-yl)-1,3-dithiol-2-yl-idene]-5-methyl-5H-1,3-dithiolo[4,5-c]pyrrole-4-carbaldehyde.2-[4,5-双(丁硫基)-1,3-二硫醇-2-亚基]-5-甲基-5H-1,3-二硫并[4,5-c]吡咯-4-甲醛
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 30;66(Pt 12):o3353. doi: 10.1107/S160053681004910X.
2
Ethyl 2-[4,5-bis-(butyl-sulfan-yl)-1,3-dithiol-2-yl-idene]-1,3-dithiolo[4,5-c]pyrrole-4-carboxyl-ate.2-[4,5-双（丁硫基）-1,3-二硫醇-2-亚基]-1,3-二硫并[4,5-c]吡咯-4-羧酸乙酯
Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):o1400. doi: 10.1107/S1600536812015309. Epub 2012 Apr 18.
3
2-[4,5-Bis(ethyl-sulfan-yl)-1,3-dithiol-2-yl-idene]-5-(4-methoxy-phen-yl)-5H-1,3-dithiolo[4,5-c]pyrrole.2-[4,5-双（乙硫基）-1,3-二硫醇-2-亚基]-5-（4-甲氧基苯基）-5H-1,3-二硫并[4,5-c]吡咯
Acta Crystallogr Sect E Struct Rep Online. 2009 Nov 14;65(Pt 12):o3092. doi: 10.1107/S1600536809047424.
4
5-(4,5-Diiodo-1,3-dithiol-2-yl-idene)-4',5'-bis-(methyl-sulfan-yl)-2,2'-bi-1,3-dithiole-4(5H)-thione.5-（4,5-二碘-1,3-二硫醇-2-亚基）-4',5'-双（甲硫基）-2,2'-联-1,3-二硫醇-4（5H）-硫酮
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 23;65(Pt 11):o2831. doi: 10.1107/S1600536809042573.
5
13-[4,5-Bis(methyl-sulfan-yl)-1,3-dithiol-2-yl-idene]-6-oxa-3,9,12,14-tetra-thia-bicyclo-[9.3.0]tetra-dec-1(11)-ene.13-[4,5-双（甲基硫烷基）-1,3-二硫醇-2-亚基]-6-氧杂-3,9,12,14-四硫杂双环-[9.3.0]十四碳-1(11)-烯
Acta Crystallogr Sect E Struct Rep Online. 2009 Sep 26;65(Pt 10):o2538. doi: 10.1107/S1600536809037301.
6
5-(4-Methyl-phenyl-sulfon-yl)-1,3-dithiolo[4,5-c]pyrrole-2-thione.5-（4-甲基-苯基-磺酰基）-1,3-二硫杂环戊烯并[4,5-c]吡咯-2-硫酮
Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):o1046. doi: 10.1107/S1600536812009622. Epub 2012 Mar 14.
7
Crystal structures of three N-(aryl-sulfon-yl)-4-fluoro-benzamides.三种N-（芳基磺酰基）-4-氟苯甲酰胺的晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 Mar 31;72(Pt 4):575-82. doi: 10.1107/S2056989016005089. eCollection 2016 Apr 1.
8
(5E)-2-[4,5-Bis(methyl-sulfan-yl)-1,3-dithiol-2-yl-idene]-5-(4-iodo-1,3-dithiol-2-yl-idene)-1,3-dithio-lan-4-one.(5E)-2-[4,5-双(甲基硫烷基)-1,3-二硫醇-2-亚基]-5-(4-碘-1,3-二硫醇-2-亚基)-1,3-二硫杂环戊烷-4-酮
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 31;65(Pt 11):o2920. doi: 10.1107/S1600536809044493.
9
2-Hy-droxy-5-[(E)-(1H-indol-3-yl-methyl-idene)aza-nium-yl]benzoate.2-羟基-5-[(E)-(1H-吲哚-3-基亚甲基)氮鎓基]苯甲酸酯
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 27;66(Pt 12):o3314. doi: 10.1107/S1600536810048579.
10
5-(4,5-Diiodo-1,3-dithiol-2-yl-idene)-4',5'-bis(methyl-sulfan-yl)-2,2'-bi-1,3-dithiol-4(5H)-one.5-（4,5-二碘-1,3-二硫醇-2-亚基）-4',5'-双（甲硫基）-2,2'-联-1,3-二硫醇-4（5H）-酮
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 10;65(Pt 11):o2716. doi: 10.1107/S160053680904032X.

引用本文的文献

1
Ethyl 2-[4,5-bis-(butyl-sulfan-yl)-1,3-dithiol-2-yl-idene]-1,3-dithiolo[4,5-c]pyrrole-4-carboxyl-ate.2-[4,5-双（丁硫基）-1,3-二硫醇-2-亚基]-1,3-二硫并[4,5-c]吡咯-4-羧酸乙酯
Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):o1400. doi: 10.1107/S1600536812015309. Epub 2012 Apr 18.

本文引用的文献

1
2-[4,5-Bis(ethyl-sulfan-yl)-1,3-dithiol-2-yl-idene]-5-(4-methoxy-phen-yl)-5H-1,3-dithiolo[4,5-c]pyrrole.2-[4,5-双（乙硫基）-1,3-二硫醇-2-亚基]-5-（4-甲氧基苯基）-5H-1,3-二硫并[4,5-c]吡咯
Acta Crystallogr Sect E Struct Rep Online. 2009 Nov 14;65(Pt 12):o3092. doi: 10.1107/S1600536809047424.
2
Structure validation in chemical crystallography.化学晶体学中的结构验证
Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55. doi: 10.1107/S090744490804362X. Epub 2009 Jan 20.
3
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.