Schlaad Helmut, Diehl Christina, Gress Anja, Meyer Matthias, Demirel A Levent, Nur Yusuf, Bertin Annabelle
Max Planck Institute of Colloids and Interfaces, Colloid Department, Research Campus Golm, 14424 Potsdam, Germany.
Macromol Rapid Commun. 2010 Mar 16;31(6):511-25. doi: 10.1002/marc.200900683. Epub 2010 Jan 5.
Poly(2-alkyl-2-oxazoline)s can be regarded as pseudo-peptides or bioinspired polymers, which are available through living/controlled cationic polymerization and polymer ("click") modification procedures. Materials and solution properties may be adjusted via the nature of the side chain (hydrophilic-hydrophobic, chiral, bio-functional, etc.), opening the way to stimulus-responsive materials and complex colloidal structures in aqueous environments. Herein, we give an overview over the macromolecular engineering of polyoxazolines, including the synthesis of biohybrids, and the "smart"/bioinspired aggregation behavior in solution.
聚（2-烷基-2-恶唑啉）可被视为拟肽或仿生聚合物，可通过活性/可控阳离子聚合和聚合物（“点击”）修饰程序获得。材料和溶液性质可通过侧链的性质（亲水-疏水、手性、生物功能等）进行调节，为水性环境中的刺激响应材料和复杂胶体结构开辟了道路。在此，我们概述了聚恶唑啉的大分子工程，包括生物杂化物的合成以及溶液中的“智能”/仿生聚集行为。
