Munteanu Maricica, Kolb Ute, Ritter Helmut
Institut für Organische Chemie und Makromolekulare Chemie, Heinrich-Heine Universität, Universitätsstrasse 1, 40225 Düsseldorf, Germany.
Macromol Rapid Commun. 2010 Apr 6;31(7):616-8. doi: 10.1002/marc.200900754. Epub 2010 Feb 3.
We applied 1,3-dipolar cycloaddition to bind ethynylferrocene onto 6I-azido-6I-deoxycyclomaltoheptaose under microwave assisted conditions. The process was investigated by (1) H NMR, FT-IR spectroscopy, and MALDI-TOF mass spectrometry. The ability of the synthesized compound to self-organize to cyclic supramolecular structures was investigated by dynamic light scattering measurements and cryo-transmission electron microscopy.
我们在微波辅助条件下应用1,3-偶极环加成反应将乙炔基二茂铁连接到6I-叠氮基-6I-脱氧环麦芽七糖上。通过¹H NMR、傅里叶变换红外光谱和基质辅助激光解吸电离飞行时间质谱对该过程进行了研究。通过动态光散射测量和低温透射电子显微镜研究了合成化合物自组装成环状超分子结构的能力。
