State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, PR China.
Chem Rec. 2011 Jun;11(3):158-71. doi: 10.1002/tcr.201100002. Epub 2011 May 19.
The latest advances in the area of polyoxometalate (POM)-based inorganic/organic hybrid materials prepared by self-assembly, covalent modification, and supramolecular interactions are presented. This Review is composed of five sections and documents the effect of organic cations on the formation of novel POMs, surfactant encapsulated POM-based hybrids, polymeric POM/organic hybrid materials, POMs-containing ionic crystals, and covalently functionalized POMs. In addition to their role in the charge-balancing, of anionic POMs, the crucial role of organic cations in the formation and functionalization of POM-based hybrid materials is discussed.
本文综述了通过自组装、共价修饰和超分子相互作用制备的多金属氧酸盐（POM）基无机/有机杂化材料的最新进展。本文由五个部分组成，记录了有机阳离子对新型 POM、表面活性剂封装的基于 POM 的杂化物、聚合 POM/有机杂化材料、含 POM 的离子晶体和共价功能化 POM 的形成的影响。除了在平衡阴离子 POM 的电荷方面的作用外，本文还讨论了有机阳离子在 POM 基杂化材料的形成和功能化中的关键作用。
