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铼（I）三羰基配合物与双齿配体邻-（二苯基膦基）苯甲醛（P∩O）和邻-[(二苯基膦基亚苄基)]苯胺（P∩N）的合成与结构表征

Synthesis and structural characterization of rhenium(I) tricarbonyl complexes with the bidentate ligands o-(diphenylphosphino)benzaldehyde (P∩O) and o-[(diphenylphosphino)benzylidene]analine (P∩N).

作者信息

Chen Xiaoyuan, Femia Frank J, Babich John W, Zubieta Jon

机构信息

Department of Chemistry, Syracuse University, Syracuse, NY 13244, USA.

出版信息

Inorganica Chim Acta. 2001 Apr 27;315(2):147-152. doi: 10.1016/S0020-1693(01)00302-4.

DOI:10.1016/S0020-1693(01)00302-4
PMID:21603092
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3098572/
Abstract

A series of rhenium(I) tricarbonyl complexes with bidentate P,O donor ligand o-(diphenylphosphino)benzaldehyde (P∩O) and its Schiff base P,N donor ligand o-[diphenylphosphino)benzylidene]analine (P∩N) have been synthesized and structurally characterized. All the complexes of the type [ReX(CO)(3)(LL)] (where LL = P∩O, P∩N) reveal a distorted octahedral structure with the three carbonyl ligands arranged in the facial fashion. Crystal data for 1, C(22)H(15)ClO(4)PRe·1/2C(6)H(14): triclinic, P1, a=8.7430(4), b=9.5767(4), c=13.9449(6) Å, α=93.651(1), β=101.265(1), γ=93.048(1); V=1140.20(9) Å(3), Z=2.2, C(22)H(15)BrO(4)Pre: monoclinic, C2/c, a=31.6800(16), b=8.8880(4), c=18.4517(9) Å, β=124.990(1); V=4256.4(4) Å(3), Z=8. 3, C(28)H(20)ClNO(3)Pre: monoclinic, C2/c, a=22.675(4), b=8.803(2), c=28.218(5) Å, β=100.192(3); V=5543.5(16) Å(3), Z=8.4, C(28)H(20)BrNO(3)Pre: monoclinic, C2/c, a=23.035(1), b=8.7561(4), c=28.269(1) Å, β=100.811(1); V=5600.4(5) Å(3), Z=8.

摘要

合成并表征了一系列含双齿P，O供体配体邻（二苯基膦基）苯甲醛（P∩O）及其席夫碱P，N供体配体邻[（二苯基膦基亚苄基）]苯胺（P∩N）的铼（I）三羰基配合物。所有[ReX(CO)₃(LL)]型配合物（其中LL = P∩O，P∩N）均呈现扭曲的八面体结构，三个羰基配体呈面式排列。配合物1，C₂₂H₁₅ClO₄PRe·1/2C₆H₁₄的晶体数据：三斜晶系，P1，a = 8.7430(4)，b = 9.5767(4)，c = 13.9449(6) Å，α = 93.651(1)，β = 101.265(1)，γ = 93.048(1)；V = 1140.20(9) ų，Z = 2.2；C₂₂H₁₅BrO₄Re：单斜晶系，C2/c，a = 31.6800(16)，b = 8.8880(4)，c = 18.4517(9) Å，β = 124.990(1)；V = 4256.4(4) ų，Z = 8；配合物3，C₂₈H₂₀ClNO₃Re：单斜晶系，C2/c，a = 22.675(4)，b = 8.803(2)，c = 28.218(5) Å，β = 100.192(3)；V = 5543.5(16) ų，Z = 8；配合物4，C₂₈H₂₀BrNO₃Re：单斜晶系，C2/c，a = 23.035(1)，b = 8.7561(4)，c = 28.269(1) Å，β = 100.811(1)；V = 5600.4(5) ų，Z = 8 。

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