• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

反式-溴代三羰基[2-(二异丙基膦基)苯甲醛-κ(2)O,P]铼(I)

fac-Bromidotricarbonyl[2-(diisopropylphosphanyl)benzaldehyde-κ(2)O,P]rhenium(I).

作者信息

Apostolidis Christos, Ahlmann Martin, Walter Olaf

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):m1201. doi: 10.1107/S1600536812035957. Epub 2012 Aug 23.

DOI:10.1107/S1600536812035957
PMID:22969489
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3435616/
Abstract

The structure of the title complex, [ReBr(C(13)H(19)OP)(CO)(3)], displays a facial coordination of the three CO ligands and a κ(2)O,P coordination mode of the 2-diisopropyl-phosphino-benzaldehyde ligands. The Re-C bond distance for the CO ligand trans to the P atom is, due to its trans influence, elongated to 1.943 (3) Å, showing that this CO ligand is more weakly bound to the Re centre than the other two.

摘要

标题配合物[ReBr(C₁₃H₁₉OP)(CO)₃]的结构显示出三个CO配体的面式配位以及2-二异丙基膦基苯甲醛配体的κ²O,P配位模式。由于P原子的反位影响，与P原子反位的CO配体的Re-C键长延长至1.943(3) Å，这表明该CO配体与Re中心的结合比其他两个CO配体更弱。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0668/3435616/9698db70d8f9/e-68-m1201-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0668/3435616/9698db70d8f9/e-68-m1201-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0668/3435616/9698db70d8f9/e-68-m1201-fig1.jpg

相似文献

1
fac-Bromidotricarbonyl[2-(diisopropylphosphanyl)benzaldehyde-κ(2)O,P]rhenium(I).反式-溴代三羰基[2-(二异丙基膦基)苯甲醛-κ(2)O,P]铼(I)
Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):m1201. doi: 10.1107/S1600536812035957. Epub 2012 Aug 23.
2
[N,N-Bis(diphenyl-phosphino)propyl-amine-κP,P]bromidotricarbonyl-rhenium(I).[二（二苯基膦基）丙基胺-κP，P]溴代三羰基铼（I）
Acta Crystallogr Sect E Struct Rep Online. 2009 Nov 14;65(Pt 12):m1575-6. doi: 10.1107/S1600536809047242.
3
Development of novel water-soluble, organometallic compounds for potential use in nuclear medicine: synthesis, characterization, and (1)H and (31)P NMR investigations of the complexes fac-[ReBr(CO)3L] (L=bis(bis(hydroxymethyl)phosphino)ethane, bis(bis(hydroxymethyl)phosphino)benzene).用于核医学潜在应用的新型水溶性有机金属化合物的开发：配合物fac-[ReBr(CO)₃L]（L = 双（双（羟甲基）膦基）乙烷、双（双（羟甲基）膦基）苯）的合成、表征以及¹H和³¹P NMR研究
Inorg Chem. 2001 May 7;40(10):2358-62. doi: 10.1021/ic001284r.
4
Chemical and biological characterization of technetium(I) and Rhenium(I) tricarbonyl complexes with dithioether ligands serving as linkers for coupling the Tc(CO)(3) and Re(CO)(3) moieties to biologically active molecules.锝（I）和铼（I）三羰基配合物与二硫醚配体的化学和生物学特性，二硫醚配体作为将Tc(CO)₃和Re(CO)₃部分与生物活性分子偶联的连接体。
Bioconjug Chem. 2000 May-Jun;11(3):414-24. doi: 10.1021/bc990162o.
5
Synthesis of Re tricarbonyl complexes with various sulfur- and oxygen-donating ligands: crystal structures of two Re dinuclear structures bridged by S atoms.
Acta Crystallogr C Struct Chem. 2018 Oct 1;74(Pt 10):1116-1122. doi: 10.1107/S205322961801207X. Epub 2018 Sep 13.
6
Silver(I) and rhenium(I) metal complexes of a 2,2'-bipyridine-functionalized third-generation tris(pyrazolyl)methane ligand.一种2,2'-联吡啶功能化的第三代三（吡唑基）甲烷配体的银（I）和铼（I）金属配合物。
Acta Crystallogr C Struct Chem. 2016 Nov 1;72(Pt 11):826-831. doi: 10.1107/S2053229616012171. Epub 2016 Oct 5.
7
Tetra-ethyl-ammonium (acetyl-acetonato)bromidotricarbonyl-rhenate(I).四乙基铵（乙酰丙酮基）溴化三羰基铼（I）
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 4;67(Pt 1):m34-5. doi: 10.1107/S1600536810050105.
8
Crystal structure of bromido-fac-tricarbon-yl[5-phenyl-3-(pyridin-2-yl)-1H-1,2,4-triazole-κ(2) N,N']rhenium(I).溴代-面式-三羰基[5-苯基-3-(吡啶-2-基)-1H-1,2,4-三唑-κ(2)N,N']铼(I)的晶体结构
Acta Crystallogr Sect E Struct Rep Online. 2014 Nov 29;70(Pt 12):587-9. doi: 10.1107/S1600536814025604. eCollection 2014 Dec 1.
9
Parametrization of the contribution of mono- and bidentate ligands on the symmetric C[triple bond]O stretching frequency of fac-[Re(CO)(3)](+) complexes.对称 C[三键]O 伸缩频率中单核和双齿配体对 fac-[Re(CO)3](+) 配合物贡献的参数化。
Inorg Chem. 2009 Nov 16;48(22):10845-55. doi: 10.1021/ic901223t.
10
Rhenium-mediated coupling of acetonitrile and pyrazoles. New molecular clefts for anion binding.铼介导的乙腈与吡唑的偶联反应。用于阴离子结合的新型分子裂缝。
Inorg Chem. 2006 Aug 21;45(17):7018-26. doi: 10.1021/ic0607078.

本文引用的文献

1
Synthesis and structural characterization of rhenium(I) tricarbonyl complexes with the bidentate ligands o-(diphenylphosphino)benzaldehyde (P∩O) and o-[(diphenylphosphino)benzylidene]analine (P∩N).铼（I）三羰基配合物与双齿配体邻-（二苯基膦基）苯甲醛（P∩O）和邻-[(二苯基膦基亚苄基)]苯胺（P∩N）的合成与结构表征
Inorganica Chim Acta. 2001 Apr 27;315(2):147-152. doi: 10.1016/S0020-1693(01)00302-4.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Re tricarbonyl complexes with ligands containing P,N,N and P,N,O donor atom sets: synthesis and structural characterization.
含磷、氮、氮和磷、氮、氧供体原子组的配体的三羰基铼配合物：合成与结构表征
Inorg Chem. 2001 Sep 24;40(20):5147-51. doi: 10.1021/ic010417l.