[closo-B12H12](2-)的催化羟化作用。——佩里亚纳反应在多面体硼烷中的适应性。
Catalytic hydroxylation of [closo-B12H12](2-)-adaptation of the Periana reaction to a polyhedral borane.
机构信息
International Institute of Nano & Molecular Medicine (I2NM2), University of Missouri, 1514 Research Park drive, Columbia, MO 65211, USA.
出版信息
Chem Commun (Camb). 2011 Jun 28;47(24):6978-80. doi: 10.1039/c1cc11722j. Epub 2011 May 23.
PMID:21603708
Abstract
Per-B-hydroxylation of a polyhedral borane anion has been demonstrated by the catalytic hydroxylation of icosahedral closo-B(12)H(12) using soft electrophiles such as platinum group metal catalysts or iodine cation. A new route to closo-B(12)(OH)(12) from closo-B(12)H(12) without the use of H(2)O(2) oxidant provides an alternative hydroxylation process.
摘要
已通过使用软亲电试剂（如铂族金属催化剂或碘阳离子）催化多面体硼烷阴离子的 Per-B-羟化反应来证明了这一点。一种无需使用 H(2)O(2)氧化剂即可从closo-B(12)H(12)制备closo-B(12)(OH)(12)的新途径为羟化反应提供了另一种选择。
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