头-尾型环糊精基绝缘分子线的合成。

Synthesis of a head-to-tail-type cyclodextrin-based insulated molecular wire.

机构信息

Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 615-8510, Japan.

出版信息

Chem Commun (Camb). 2011 Jun 28;47(24):6816-8. doi: 10.1039/c1cc12231b. Epub 2011 May 23.

DOI:10.1039/c1cc12231b

PMID:21603719

Abstract

We developed a new method for synthesizing an organic-soluble insulated molecular wire (IMW) using permethylated cyclodextrin (PMCD). The IMW obtained using this method is highly soluble in a variety of organic solvents and has a high covering ratio, regioregularity, rigidity, photoluminescence efficiency, and interchain hole mobility.

摘要

我们开发了一种使用全甲基化环糊精（PMCD）合成有机可溶性绝缘分子线（IMW）的新方法。使用该方法获得的 IMW 在各种有机溶剂中具有高溶解性、高覆盖比、区域规整性、刚性、光致发光效率和链间空穴迁移率。