一种刚性镧系元素结合标签，用于碳水化合物的 NMR 结构分析。
A rigid lanthanide binding tag for NMR structural analysis of carbohydrates.
机构信息
Facultad de Farmacia, Dpto. Química, Universidad San Pablo CEU, Urb. Montepríncipe, ctra. Boadilla km 5, 300 Boadilla del Monte, 28668 Madrid, Spain.
出版信息
Chem Commun (Camb). 2011 Jul 7;47(25):7179-81. doi: 10.1039/c1cc11860a. Epub 2011 May 23.
PMID:21607252
Abstract
The first synthesis of a carbohydrate molecule covalently bound to a rigid lanthanide binding tag is reported. This derivative has been designed as a new tool to provide long-range restraints for structural elucidation and molecular recognition studies of carbohydrates, thus extending the methodology already developed for proteins.
摘要
首次报道了一种碳水化合物分子与刚性镧系元素结合标签共价结合的合成。该衍生物被设计为一种新的工具，为碳水化合物的结构阐明和分子识别研究提供远程约束，从而扩展了已经为蛋白质开发的方法。
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