钯催化 H-膦酸酯与氯代芳烃的交叉偶联反应。
Palladium-catalyzed cross-coupling of H-phosphinate esters with chloroarenes.
机构信息
Department of Chemistry, Box 298860, Texas Christian University, Fort Worth, Texas 76129, USA.
出版信息
Org Lett. 2011 Jun 17;13(12):3270-3. doi: 10.1021/ol201222n. Epub 2011 May 25.
PMID:21612265
Abstract
The palladium-catalyzed cross-coupling reaction between H-phosphinate esters and chloroarenes or chloroheteroarenes is described. This reaction is the first general metal-catalyzed phosphorus-carbon bond-forming reaction between a phosphorus nucleophile and chloroarenes.
摘要
钯催化的 H-膦酸酯酯与氯代芳烃或氯代杂芳烃的交叉偶联反应被描述。该反应是首例磷亲核试剂与氯代芳烃之间的通用金属催化的磷-碳键形成反应。
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