Department of Chemistry and Key Laboratory for Chemical Biology of Fujian Province, College of Chemistry and Chemical Engineering, Xiamen University , Xiamen 361005, Fujian, China.
Org Lett. 2013 Oct 18;15(20):5362-5. doi: 10.1021/ol402672e. Epub 2013 Oct 7.
A novel and efficient Ni-catalyzed coupling of a wide range of arylboronic acids with H-phosphites, H-phosphinate esters, and H-phosphine oxides has been developed, providing a general and powerful tool for the synthesis of various aryl-phosphorus compounds, especially for valuable triarylphosphine oxides, in good to excellent yield. This protocol is the first Ni-catalyzed C-P bond-forming reaction between arylboronic acids and P(O)H compounds.
一种新型高效的镍催化反应，能够使各种芳基硼酸与 H-膦酸酯、H-膦酸酯和 H-氧化膦偶联，为合成各种芳基-磷化合物，特别是有价值的三芳基氧化膦，提供了一种通用且强大的工具，产率良好到优秀。该方案是首例镍催化芳基硼酸与 P（O）H 化合物之间的 C-P 键形成反应。
