基于色氨酸的吡啶酰胺配体的铽(III)和铕(III)发光配合物的镧系元素导向自组装形成。
Lanthanide directed self-assembly formations of Tb(III) and Eu(III) luminescent complexes from tryptophan based pyridyl amide ligands.
机构信息
School of Chemistry, Centre for Synthesis and Chemical Biology, Trinity College Dublin, Dublin 2, Ireland.
出版信息
Chem Commun (Camb). 2011 Jul 7;47(25):7119-21. doi: 10.1039/c1cc11326g. Epub 2011 May 26.
PMID:21614366
Abstract
The formation of self-assembly complexes between the ligands 1 (SS) and 2 (RR) and terbium or europium was undertaken and shown (using various spectroscopic titrations) to give rise to the exclusive formation of 2:1 (L:Ln) stoichiometry and not the anticipated 3:1 stoichiometry.
摘要
开展了配体 1（SS）和 2（RR）与铽或铕之间自组装配合物的形成研究，并通过各种光谱滴定表明，只形成了 2:1（L:Ln）的化学计量比，而不是预期的 3:1 化学计量比。
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