氢键自组装的稳定卟啉笼的分级组织。
Hierarchical organization of a robust porphyrin cage self-assembled by hydrogen bonds.
机构信息
Department of Chemistry & Biochemistry, Hunter College of The City University of New York, 695 Park Avenue, New York, NY 10065, USA.
出版信息
Chem Commun (Camb). 2011 Jul 7;47(25):7134-6. doi: 10.1039/c1cc11553g. Epub 2011 May 25.
Abstract
Porphyrins appended with four rigid hydrogen bonding motifs on the meso positions were synthesized and self-assembled into a cofacial cage with four complementary bis(decyl)melamine units in dry solvents. The hydrocarbon chains on the melamine mediate the formation of nanofilms on surfaces as the solvent slowly evaporates.
摘要
在卟啉的中位处连接了四个刚性氢键给体，在干燥溶剂中，这些卟啉可以与四个互补的双（癸基）氰胺单元自组装成一个共面笼状结构。当溶剂缓慢蒸发时，氰胺上的碳氢链可以在表面形成纳米薄膜。
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