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通过使用表面羟基化的 BaTiO₃ 纳米粒子来提高 BaTiO₃/铁电聚合物复合材料的介电性能。

Improving dielectric properties of BaTiO₃/ferroelectric polymer composites by employing surface hydroxylated BaTiO₃ nanoparticles.

机构信息

State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China.

出版信息

ACS Appl Mater Interfaces. 2011 Jul;3(7):2184-8. doi: 10.1021/am200492q. Epub 2011 Jun 10.

Abstract

Dielectric properties of poly(vinylidene fluoride) (PVDF) based nanocomposites filled with surface hydroxylated BaTiO(3) (h-BT) nanoparticles were reported. The h-BT fillers were prepared from crude BaTiO(3) (c-BT) in aqueous solution of H(2)O(2). Results showed that the dielectric properties of the h-BT/PVDF nanocomposites had weaker temperature and frequency dependences than that of c-BT/PVDF nanocomposites. Meanwhile, the h-BT/PVDF composites showed lower loss tangent and higher dielectric strength. It is suggested that the strong interaction between h-BT fillers and PVDF matrix is the main reason for the improved dielectric properties.

摘要

本文报道了表面羟基化的 BaTiO3(h-BT)纳米粒子填充的聚偏氟乙烯(PVDF)基纳米复合材料的介电性能。h-BT 填充剂是由粗 BaTiO3(c-BT)在 H2O2 的水溶液中制备的。结果表明,h-BT/PVDF 纳米复合材料的介电性能比 c-BT/PVDF 纳米复合材料具有较弱的温度和频率依赖性。同时,h-BT/PVDF 复合材料具有较低的损耗正切和较高的介电强度。研究表明,h-BT 填充剂与 PVDF 基体之间的强相互作用是改善介电性能的主要原因。

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