Department of Chemistry, University of Kentucky, Lexington, KY 40506, USA.
Chem Commun (Camb). 2011 Jul 21;47(27):7617-9. doi: 10.1039/c1cc12410b. Epub 2011 Jun 10.
Amide functionalized anthradithiophenes (ADTs) play active acceptor roles in polymer bulk-heterojunction solar cells. The first separation of ADT isomers is reported, and the regiochemistry of the ADT has significant impact on crystal packing and solar cell performance. Cell efficiency up to 0.80%, due in large part to high open-circuit voltage (V(OC) > 1.0 V), is achieved in bulk-heterojunction solar cells comprising syn-ADT and poly(3-hexylthiophene).
酰胺官能化蒽二噻吩（ADTs）在聚合物体异质结太阳能电池中充当活性受体。首次分离出 ADT 的异构体，ADT 的区域化学对晶体堆积和太阳能电池性能有显著影响。包含顺式 ADT 和聚（3-己基噻吩）的体异质结太阳能电池的效率高达 0.80%，这主要归因于开路电压（V(OC) > 1.0 V）较高。
