State Key Laboratory of Chirosciences and Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Kowloon, Hong Kong.
Chem Commun (Camb). 2011 Aug 7;47(29):8328-30. doi: 10.1039/c1cc12240a. Epub 2011 Jun 17.
A general and effective palladium system for Suzuki-Miyaura coupling of alkenyl electrophiles under mild reaction conditions is reported. With the Pd(OAc)(2)/CM-phos system, a variety of alkenyl tosylates are coupled well with ArB(OH)(2). Moreover, the first successful examples of using alkenyl mesylates in alkenylation are also described.
报道了一种在温和反应条件下用于烯基亲电试剂的 Suzuki-Miyaura 偶联的通用且有效的钯体系。使用 Pd(OAc)(2)/CM-phos 体系，各种烯基对甲苯磺酸盐与 ArB(OH)(2) 很好地偶联。此外，还描述了首例成功使用烯基甲磺酸盐进行烯基化的例子。
