WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow G1 1XL, UK.
Chem Commun (Camb). 2012 Feb 1;48(10):1541-3. doi: 10.1039/c1cc12869h. Epub 2011 Jun 17.
More usually thought of as a base, the sodium zincate [(TMEDA)·Na(μ-TMP)(μ-(t)Bu)Zn((t)Bu)] 1 can undergo single electron transfer with TEMPO to give [(TMEDA)·Na(μ-TMP)(μ-TEMPO(-))Zn((t)Bu)] 2 and [(TMEDA)·Na(μ-TEMPO(-))(2)Zn((t)Bu)] 3; and with chalcone [PhCOCH=CHPh] gives [{(TMEDA)·Na(μ-TMP)Zn((t)Bu)}(2)(μ-OCPhCH=CHPhCHPhCH=CPh-μ-O)] which contains two chalcone units C-C coupled though their benzylic C atoms.
通常被认为是碱，锌酸钠[(TMEDA)·Na(μ-TMP)(μ-(t)Bu)Zn((t)Bu)] 1 可以与 TEMPO 发生单电子转移，生成 [(TMEDA)·Na(μ-TMP)(μ-TEMPO(-))Zn((t)Bu)] 2 和 [(TMEDA)·Na(μ-TEMPO(-))(2)Zn((t)Bu)] 3；与查尔酮 [PhCOCH=CHPh] 反应生成 [{(TMEDA)·Na(μ-TMP)Zn((t)Bu)}(2)(μ-OCPhCH=CHPhCHPhCH=CPh-μ-O)]，其中包含两个通过苄基 C 原子 C-C 偶联的查尔酮单元。
