二茂铁-[4]-螺旋喹喔啉酮的合成与手性光学性质：平面手性二烯的动力学拆分。
Synthesis and chiroptical properties of ferrocene-[4]-helicenequinones: kinetic resolution of a planar-chiral diene.
机构信息
Departamento de Química Orgánica (Módulo 01), Facultad de Ciencias, Universidad Autónoma de Madrid, Cantoblanco, 28049-Madrid, Spain.
出版信息
Chem Commun (Camb). 2011 Jul 28;47(28):8103-5. doi: 10.1039/c1cc12921j. Epub 2011 Jun 20.
PMID:21687877
Abstract
Both enantiomers of ferrocene [4]-helicenequinone 6, showing planar and helical chiralities, have been synthesized with very high optical purities using, as the key step, a kinetic resolution process between planar-chiral racemic ferrocene diene 2 and enantiopure sulfinyl benzoquinone (S)-3.
摘要
[4]-螺二芴二酮 6 的两个对映异构体均具有平面和螺旋手性，已通过使用动力学拆分过程（关键步骤）在平面手性外消旋二茂铁二烯 2 和对映纯亚磺酰基苯醌 (S)-3 之间合成，光学纯度非常高。
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