Alba-Simionesco C, Coasne B, Dosseh G, Dudziak G, Gubbins K E, Radhakrishnan R, Sliwinska-Bartkowiak M
Laboratoire de Chimie Physique, CNRS-UMR 8000, Bâtiment 349, Université de Paris-Sud, F-91405 Orsay, France.
J Phys Condens Matter. 2006 Feb 15;18(6):R15-68. doi: 10.1088/0953-8984/18/6/R01. Epub 2006 Jan 23.
We present a review of experimental, theoretical, and molecular simulation studies of confinement effects on freezing and melting. We consider both simple and more complex adsorbates that are confined in various environments (slit or cylindrical pores and also disordered porous materials). The most commonly used molecular simulation, theoretical and experimental methods are first presented. We also provide a brief description of the most widely used porous materials. The current state of knowledge on the effects of confinement on structure and freezing temperature, and the appearance of new surface-driven and confinement-driven phases are then discussed. We also address how confinement affects the glass transition.
我们对限制作用对凝固和熔化的影响的实验、理论及分子模拟研究进行了综述。我们考虑了被限制在各种环境（狭缝或圆柱形孔隙以及无序多孔材料）中的简单和更复杂的吸附质。首先介绍了最常用的分子模拟、理论和实验方法。我们还简要描述了使用最广泛的多孔材料。然后讨论了关于限制对结构和凝固温度的影响以及新的表面驱动和限制驱动相的出现的当前知识状态。我们还探讨了限制如何影响玻璃化转变。
