Institut für Experimentelle und Angewandte Physik, Christian-Albrechts-Universität zu Kiel, D-24098 Kiel, Germany.
J Am Chem Soc. 2011 Jul 27;133(29):11007-9. doi: 10.1021/ja203199q. Epub 2011 Jun 30.
Single lead-phthalocyanine molecules adsorbed to ultrathin lead islands on Ag(111) are demetalized by transferring the lead atom of the inner macrocycle to the tip of a scanning tunneling microscope. Reactants and products are discriminated by their images and spectroscopic fingerprints.
吸附在 Ag(111)上超薄铅岛上的单个酞菁单分子,通过将内大环的铅原子转移到扫描隧道显微镜的针尖上来脱金属化。通过它们的图像和光谱指纹来区分反应物和产物。