Food Science Programme, School of Chemical Sciences, The University of Auckland, Auckland, New Zealand.
J Agric Food Chem. 2011 Aug 10;59(15):8358-65. doi: 10.1021/jf201469c. Epub 2011 Jul 14.
The glycosidically bound volatile fraction of baby kiwi ( Actinidia arguta ) was studied. Glycosidic precursors were isolated from juice by adsorption onto an Amberlite XAD-2 column. After enzymatic hydrolysis with Rapidase AR2000, the released aglycones were analyzed by GC-MS. Alcohols, terpenoids, and benzenoids were the most abundant compound classes. Aromatic compounds and norisoprenoids showed the highest concentrations. Major compounds were 2,5-dimethyl-4-hydroxy-3(2H)-furanone (Furaneol), benzyl alcohol, 3-hydroxy-β-damascone, hexanal, and (Z)-3-hexen-1-ol. Precursors of aroma compounds including benzoic acid, cinnamic acid, and coniferyl alcohol were also found. Eugenol, raspberry ketone, and 4-vinylguaiacol were identified for the first time in the fruit of an Actinidia species. The high concentration of 2,5-dimethyl-4-hydroxy-3(2H)-furanone in bound form (95.36 μg/kg) is particularly interesting and justifies further investigation.
对婴儿猕猴桃(Actinidia arguta)的糖苷结合挥发性部分进行了研究。糖苷前体通过吸附到 Amberlite XAD-2 柱上从果汁中分离出来。用 Rapidase AR2000 进行酶解后,用 GC-MS 分析释放的糖苷配基。醇类、萜类和苯类是最丰富的化合物类别。芳香族化合物和降异戊二烯类化合物的浓度最高。主要化合物为 2,5-二甲基-4-羟基-3(2H)-呋喃酮(糠醇)、苯甲醇、3-羟基-β-大马酮、己醛和(Z)-3-己烯-1-醇。还发现了包括苯甲酸、肉桂酸和松柏醇在内的香气化合物的前体。首次在猕猴桃属植物的果实中鉴定出了丁子香酚、覆盆子酮和 4-乙烯基愈创木酚。结合形式(95.36μg/kg)中 2,5-二甲基-4-羟基-3(2H)-呋喃酮的高浓度特别有趣,值得进一步研究。