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characterization of the bound volatile extract from baby kiwi (actinidia arguta).

Characterization of the bound volatile extract from baby kiwi (Actinidia arguta).

机构信息

Food Science Programme, School of Chemical Sciences, The University of Auckland, Auckland, New Zealand.

出版信息

J Agric Food Chem. 2011 Aug 10;59(15):8358-65. doi: 10.1021/jf201469c. Epub 2011 Jul 14.

Abstract

The glycosidically bound volatile fraction of baby kiwi ( Actinidia arguta ) was studied. Glycosidic precursors were isolated from juice by adsorption onto an Amberlite XAD-2 column. After enzymatic hydrolysis with Rapidase AR2000, the released aglycones were analyzed by GC-MS. Alcohols, terpenoids, and benzenoids were the most abundant compound classes. Aromatic compounds and norisoprenoids showed the highest concentrations. Major compounds were 2,5-dimethyl-4-hydroxy-3(2H)-furanone (Furaneol), benzyl alcohol, 3-hydroxy-β-damascone, hexanal, and (Z)-3-hexen-1-ol. Precursors of aroma compounds including benzoic acid, cinnamic acid, and coniferyl alcohol were also found. Eugenol, raspberry ketone, and 4-vinylguaiacol were identified for the first time in the fruit of an Actinidia species. The high concentration of 2,5-dimethyl-4-hydroxy-3(2H)-furanone in bound form (95.36 μg/kg) is particularly interesting and justifies further investigation.

摘要

对婴儿猕猴桃(Actinidia arguta)的糖苷结合挥发性部分进行了研究。糖苷前体通过吸附到 Amberlite XAD-2 柱上从果汁中分离出来。用 Rapidase AR2000 进行酶解后,用 GC-MS 分析释放的糖苷配基。醇类、萜类和苯类是最丰富的化合物类别。芳香族化合物和降异戊二烯类化合物的浓度最高。主要化合物为 2,5-二甲基-4-羟基-3(2H)-呋喃酮(糠醇)、苯甲醇、3-羟基-β-大马酮、己醛和(Z)-3-己烯-1-醇。还发现了包括苯甲酸、肉桂酸和松柏醇在内的香气化合物的前体。首次在猕猴桃属植物的果实中鉴定出了丁子香酚、覆盆子酮和 4-乙烯基愈创木酚。结合形式(95.36μg/kg)中 2,5-二甲基-4-羟基-3(2H)-呋喃酮的高浓度特别有趣,值得进一步研究。

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