Nagao Yu, Takasu Akinori
Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan.
Macromol Rapid Commun. 2009 Feb 2;30(3):199-203. doi: 10.1002/marc.200800529. Epub 2009 Jan 7.
A "click" polymerization of dialkynes that contain an ester linkages and diazides to has been performed to synthesize various polyesters, termed "click polyesters" with a high $\overline M _{\rm n}$ of 1.0 × 10(4) to 7.0 × 10(4) in an excellent yield. This polymerization accompanied a formation of 1,4-disubstituted triazoles in the polyester main chain by a Cu(I) catalyst. The triazole ring formation in the polyester main chain leads to improved thermal properties and enhancement of the even-odd effect of methylene chain length of the produced click polyesters. This report is the first report of the application of click chemistry to synthesize a series of polyesters under mild conditions.
