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铃木缩聚反应:定制聚亚芳基。

Suzuki Polycondensation: Polyarylenes à la Carte.

作者信息

Sakamoto Junji, Rehahn Matthias, Wegner Gerhard, Schlüter A Dieter

机构信息

Department of Materials, HCI J541, ETH Zürich, Wolfgang-Pauli-Strasse 10, 8093 Zürich, Switzerland.

出版信息

Macromol Rapid Commun. 2009 May 19;30(9-10):653-87. doi: 10.1002/marc.200900063.

Abstract

This review draws a rather comprehensive picture of how Suzuki polycondensation was discovered in 1989 and how it was subsequently developed into the most powerful polymerization method for polyarylenes during the last 20 years. It combines insights into synthetic issues with classes of polymers prepared and touches upon aspects of this method's technological importance. Because a significant part of the developmental work was carried out in industry, the present review makes reference to an unusually large number of patents.

摘要

这篇综述较为全面地描绘了1989年铃木缩聚反应是如何被发现的,以及在过去20年里它是如何随后发展成为制备聚亚芳基最强大的聚合方法的。它将对合成问题的见解与所制备的聚合物类别相结合,并涉及了该方法在技术方面的重要性。由于相当一部分开发工作是在工业领域进行的,因此本综述引用了数量异常众多的专利。

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