KAUST Catalysis Centre (KCC), King Abdullah University of Science and Technology (KAUST), Thuwal 23955, KSA.
Chem Soc Rev. 2011 Oct;40(10):5181-203. doi: 10.1039/c1cs15079k. Epub 2011 Aug 1.
This critical review deals with the applications of nanocatalysts in Suzuki coupling reactions, a field that has attracted immense interest in the chemical, materials and industrial communities. We intend to present a broad overview of nanocatalysts for Suzuki coupling reactions with an emphasis on their performance, stability and reusability. We begin the review with a discussion on the importance of Suzuki cross-coupling reactions, and we then discuss fundamental aspects of nanocatalysis, such as the effects of catalyst size and shape. Next, we turn to the core focus of this review: the synthesis, advantages and disadvantages of nanocatalysts for Suzuki coupling reactions. We begin with various nanocatalysts that are based on conventional supports, such as high surface silica, carbon nanotubes, polymers, metal oxides and double hydroxides. Thereafter, we reviewed nanocatalysts based on non-conventional supports, such as dendrimers, cyclodextrin and magnetic nanomaterials. Finally, we discuss nanocatalyst systems that are based on non-conventional media, i.e., fluorous media and ionic liquids, for use in Suzuki reactions. At the end of this review, we summarise the significance of nanocatalysts, their impacts on conventional catalysis and perspectives for further developments of Suzuki cross-coupling reactions (131 references).
这篇评论性文章主要讨论了纳米催化剂在铃木偶联反应中的应用，这一领域在化学、材料和工业界引起了广泛关注。我们旨在对铃木偶联反应中的纳米催化剂进行全面概述，重点介绍它们的性能、稳定性和可重复使用性。
文章首先讨论了铃木交叉偶联反应的重要性，然后讨论了纳米催化的基本方面，如催化剂尺寸和形状的影响。接下来，我们将重点转向本评论的核心：铃木偶联反应纳米催化剂的合成、优点和缺点。我们首先介绍了各种基于传统载体的纳米催化剂，如高比表面积的二氧化硅、碳纳米管、聚合物、金属氧化物和双氢氧化物。然后，我们综述了基于非传统载体的纳米催化剂，如树状大分子、环糊精和磁性纳米材料。最后，我们讨论了基于非传统介质的纳米催化剂体系，即在铃木反应中使用氟相和离子液体。
在这篇综述的最后，我们总结了纳米催化剂的重要性、它们对传统催化的影响以及铃木交叉偶联反应进一步发展的前景（131 篇参考文献）。
