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铜基块状金属玻璃的玻璃形成、化学性质及表面分析

Glass formation, chemical properties and surface analysis of Cu-based bulk metallic glasses.

作者信息

Qin Chunling, Zhao Weimin, Inoue Akihisa

机构信息

School of Materials Science and Engineering, Hebei University of Technology, Tianjin 300132, China; E-Mail:

出版信息

Int J Mol Sci. 2011;12(4):2275-93. doi: 10.3390/ijms12042275. Epub 2011 Apr 4.

DOI:10.3390/ijms12042275
PMID:21731441
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3127117/
Abstract

This paper reviews the influence of alloying elements Mo, Nb, Ta and Ni on glass formation and corrosion resistance of Cu-based bulk metallic glasses (BMGs). In order to obtain basic knowledge for application to the industry, corrosion resistance of the Cu-Hf-Ti-(Mo, Nb, Ta, Ni) and Cu-Zr-Ag-Al-(Nb) bulk glassy alloy systems in various solutions are reported in this work. Moreover, X-ray photoelectron spectroscopy (XPS) analysis is performed to clarify the surface-related chemical characteristics of the alloy before and after immersion in the solutions; this has lead to a better understanding of the correlation between the surface composition and the corrosion resistance.

摘要

本文综述了合金元素钼、铌、钽和镍对铜基块体金属玻璃（BMG）玻璃形成能力和耐蚀性的影响。为了获得应用于工业的基础知识，本文报道了Cu-Hf-Ti-（Mo、Nb、Ta、Ni）和Cu-Zr-Ag-Al-（Nb）块体玻璃合金体系在各种溶液中的耐蚀性。此外，还进行了X射线光电子能谱（XPS）分析，以阐明合金在溶液浸泡前后与表面相关的化学特性；这有助于更好地理解表面成分与耐蚀性之间的关系。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/50e2/3127117/aef367f9204b/ijms-12-02275f13.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/50e2/3127117/5a71f0c3ede4/ijms-12-02275f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/50e2/3127117/f62b11939b3e/ijms-12-02275f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/50e2/3127117/d3dc37afecc8/ijms-12-02275f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/50e2/3127117/2e915a409a8c/ijms-12-02275f11.jpg
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本文引用的文献

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Materials (Basel). 2022 Mar 15;15(6):2172. doi: 10.3390/ma15062172.