甜（杂）芳烃：糖模拟物构建的糖基化模板。
Sweet (hetero)aromatics: glycosylated templates for the construction of saccharide mimetics.
机构信息
Institute for Organic Chemistry, University of Mainz, Duesbergweg 10-14, 55128 Mainz, Germany.
出版信息
Chem Commun (Camb). 2011 Aug 28;47(32):9212-4. doi: 10.1039/c1cc13078a. Epub 2011 Jul 11.
PMID:21743917
Abstract
Mono- and diglycosylated aromatics and heteroaromatics may serve as building blocks for the construction of metabolically stable mimetics of oligosaccharides. Methods for their preparation from monosaccharidic precursors by direct C-glycosylation, dipolar cycloaddition or Larock cyclization are described.
摘要
单糖和二糖芳基和杂芳基可以作为构建代谢稳定的寡糖类似物的构建块。本文描述了通过直接 C-糖苷化、偶极环加成或 Larock 环化从单糖前体制备它们的方法。
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