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[网络热力学在微系统输运解释中的应用:均相溶液通过聚合物膜的输运]

[Application of the network thermodynamics to interpretation of transport in a microsystems: transport of homogeneous solutions through polymeric membrane].

作者信息

Slezak Andrzej

机构信息

Katedra Zdrowia Publicznego Politechnika Czestochowska, Czestochowa.

出版信息

Polim Med. 2011;41(1):29-41.

PMID:21744656
Abstract

The Kedem-Katchalsky equations, derived using symmetric and hybrid transformation of the Peusner's network transformation, to interpretation of transport through Nephrophan membrane of glucose aqueous solutions were employed. The values of Rij, Lij, Hij i Pij (i does not = j = 1, 2) coefficients were calculated. From these calculations it results that, the values of coefficients R12, L11 and H11 are independent on concentration (C). The values of residual coefficients are dependent on C: values of coefficients P11, L12, L22 and H22 increases linearly, while values of coefficients R22 and P22--hiperbolic decreases together with growth of C. In turn the coefficient H12 is negative and coefficients P11 and P12 are positive. The values of these coefficients decreases together with growth of C.

摘要

采用通过对Peusner网络变换进行对称和混合变换推导得出的Kedem-Katchalsky方程,来解释葡萄糖水溶液通过Nephrophan膜的传输。计算了Rij、Lij、Hij和Pij(i≠j = 1, 2)系数的值。从这些计算结果可知,系数R12、L11和H11的值与浓度(C)无关。残余系数的值与C有关:系数P11、L12、L22和H22的值随C的增加呈线性增加,而系数R22和P22的值则随C的增加呈双曲线下降。反过来,系数H12为负,系数P11和P12为正。这些系数的值随C的增加而减小。

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