Thomas Priya A, Marvey Bassie B, Ebenso Eno E
Department of Chemistry, North-West University (Mafikeng Campus), Private Bag X2046, Mmabatho 2735, South Africa; E-Mail:
Int J Mol Sci. 2011;12(6):3989-97. doi: 10.3390/ijms12063989. Epub 2011 Jun 14.
The self-metathesis of methyl oleate and methyl ricinoleate was carried out in the presence of ruthenium alkylidene catalysts 1-4 in [bmim] and [bdmim][X] type ionic liquids (RTILs) (X = PF(6) (-), BF(4) (-) and NTf(2) (-)) using the gas chromatographic technique. Best catalytic performance was obtained in [bdmim][X] type ionic liquids when compared with [bmim][X] type ionic liquids. Catalyst recycling studies were also carried out in the room temperature ionic liquids (RTILs) with catalysts 1-4 in order to explore their possible industrial application.
在离子液体（RTILs）（[bmim]和[bdmim][X]型，X = PF(6) (-)、BF(4) (-)和NTf(2) (-)）存在的情况下，使用气相色谱技术进行油酸甲酯和蓖麻油酸甲酯的自复分解反应，所用催化剂为钌亚烷基催化剂1 - 4。与[bmim][X]型离子液体相比，[bdmim][X]型离子液体具有最佳的催化性能。还在室温离子液体（RTILs）中使用催化剂1 - 4进行了催化剂循环利用研究，以探索其可能的工业应用。
