（4,5-二氮杂芴-9-酮-κN,N'）双（硫氰酸根合-κS）汞（II）
(4,5-Diaza-fluoren-9-one-κN,N')bis-(thio-cyanato-κS)mercury(II).
作者信息
Notash Behrouz, Safari Nasser, Amani Vahid
机构信息
Department of Chemistry, Shahid Beheshti University, G. C., Evin, Tehran 1983963113, Iran.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m418. doi: 10.1107/S1600536811008142. Epub 2011 Mar 9.
Abstract
In the title compound, [Hg(NCS)(2)(C(11)H(6)N(2)O)], the Hg(II) atom, lying on a twofold rotation axis, is four-coordinated in a distorted tetra-hedral geometry by an N,N'-bidentate diaza-fluoren-9-one ligand and two thio-cyanate anions. In the crystal, inter-molecular C-H⋯N and C-H⋯O hydrogen bonds are effective in the stabilization of the structure.
摘要
在标题化合物[Hg(NCS)₂(C₁₁H₆N₂O)]中，位于二重旋转轴上的Hg(II)原子通过一个N,N'-双齿二氮杂芴-9-酮配体和两个硫氰酸根阴离子以扭曲的四面体几何构型进行四配位。在晶体中，分子间的C-H⋯N和C-H⋯O氢键对结构的稳定起有效作用。
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