μ-1,6-双（二苯基砷基）己烷]双[氯化金（I）]
μ-1,6-Bis(diphenyl-arsan-yl)hexa-ne]bis-[chloridogold(I).
作者信息
Shawkataly Omar Bin, Tariq Abu, Khan Imthyaz Ahmad, Yeap Chin Sing, Fun Hoong-Kun
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m427-8. doi: 10.1107/S1600536811008646. Epub 2011 Mar 12.
Abstract
In the title compound, [Au(2)Cl(2)(C(30)H(32)As(2))], each Au atom is coordinated by As and Cl atoms in an approximately linear geometry. In the crystal, mol-ecules are linked into two-dimensional networks parallel to the ac plane via inter-molecular C-H⋯Cl inter-actions. One of the phenyl rings is disordered over two positions, with site occupancies of 0.518 (8) and 0.482 (8).
摘要
在标题化合物[Au₂Cl₂(C₃₀H₃₂As₂)]中，每个金原子由砷和氯原子以近似线性的几何构型配位。在晶体中，分子通过分子间的C—H⋯Cl相互作用连接成平行于ac平面的二维网络。其中一个苯环在两个位置上无序，占位比为0.518 (8) 和0.482 (8)。
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