高氯酸苄铵-18-冠-6（1/1）
Benzyl-aminium perchlorate-18-crown-6 (1/1).
作者信息
Wang Wen-Zhe, Li Xiu-Juan, Wang Na
机构信息
RiZhao Polytechnic, RiZhao 276826, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):o772. doi: 10.1107/S1600536811007082. Epub 2011 Mar 2.
Abstract
In the title compound, C(7)H(10)N(+)·ClO(4) (-)·C(20)H(24)O(6), the proton-ated benzyl-amine cation forms a rotator-stator complex with the 18-crown-6 (1,4,7,10,13,16-hexa-oxacyclo-octa-deca-ne) mol-ecule via N-H⋯O hydrogen bonds. The cations are associated via weak C-H⋯π inter-actions, forming chains parallel to [011], while the perclorate anions are located between these chains.
摘要
在标题化合物C₇H₁₀N⁺·ClO₄⁻·C₂₀H₂₄O₆中，质子化苄胺阳离子通过N-H⋯O氢键与18-冠-6（1,4,7,10,13,16-六氧杂环十八烷）分子形成转子-定子配合物。阳离子通过弱C-H⋯π相互作用缔合，形成平行于[011]的链，而高氯酸根阴离子位于这些链之间。
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