(3aR,6S,7aR)-7a-溴-2-[(4-甲基苯基)磺酰基]-1,2,3,6,7,7a-六氢-3a,6-环氧异吲哚
(3aR,6S,7aR)-7a-Bromo-2-[(4-methyl-phen-yl)sulfon-yl]-1,2,3,6,7,7a-hexa-hydro-3a,6-ep-oxy-isoindole.
作者信息
Koşar Başak, Demircan Aydın, Arslan Hakan, Büyükgüngör Orhan
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):o994-5. doi: 10.1107/S1600536811010750. Epub 2011 Mar 31.
Abstract
In the title compound, C(15)H(16)BrNO(3)S, the boat form of the six-membered ring is almost symmetrical with respect to the ep-oxy bridge. The two five-membered rings generated by the ep-oxy bridge of the six-membered ring adopt envelope conformations, whereas the N-containing five-membered ring adopts a twisted conformation. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds.
摘要
在标题化合物C₁₅H₁₆BrNO₃S中，六元环的船式构象相对于环氧桥几乎是对称的。由六元环的环氧桥生成的两个五元环呈信封式构象，而含氮五元环呈扭曲构象。在晶体中，分子通过C—H⋯O氢键相连。
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