(3aR,6S,7aR)-7a-氯-6-甲基-2-(4-硝基苯基磺酰基)-1,2,3,6,7,7a-六氢-3a,6-环氧异吲哚
(3aR,6S,7aR)-7a-Chloro-6-methyl-2-(4-nitro-phenyl-sulfon-yl)-1,2,3,6,7,7a-hexa-hydro-3a,6-ep-oxy-iso-indole.
作者信息
Demircan Aydın, Temel Ersin, Kandemir Muhammet Kasım, Colak Medine, Büyükgüngör Orhan
机构信息
Department of Chemistry, Faculty of Arts and Sciences, Niĝde University, TR-51240 Niĝde, Turkey.
Ondokuz Mayıs University, Arts and Sciences Faculty, Department of Physics, TR-55139 Samsun, Turkey.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2013 Oct 9;69(Pt 11):o1628-9. doi: 10.1107/S1600536813026329.
In the title compound, C15H15ClN2O5S, the tetra-hydro-furan ring adopts an envelope conformation with the O atom as the flap. The pyrrolidine ring adopts an envelope conformation with the chlorine-substituted C atom as the flap. In the crystal, two types of C-H⋯O hydrogen bonds generate R (2) 2(20) and R (4) 4(26) rings, with adjacent rings running parallel to ac plane. Further C-H⋯O hydrogen bonds form a C(6) chain, linking the mol-ecules in the b-axis direction.
在标题化合物C₁₅H₁₅ClN₂O₅S中，四氢呋喃环呈信封式构象，以O原子为折叶。吡咯烷环呈信封式构象，以氯取代的C原子为折叶。在晶体中，两种类型的C—H⋯O氢键形成R(2)₂(20)和R(4)₄(26)环，相邻环平行于ac平面排列。进一步的C—H⋯O氢键形成一条C(6)链，在b轴方向连接分子。
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