（3a,6,6a,7,11b,11c）-2,2-二苄基-2,3,6a,11c-四氢-1,6,7-3a,6:7,11b-二环氧二苯并[，]异喹啉-2-鎓三氟甲磺酸盐的晶体结构和 Hirshfeld 表面分析

Crystal structure and Hirshfeld surface analysis of (3a,6,6a,7,11b,11c)-2,2-dibenzyl-2,3,6a,11c-tetra-hydro-1,6,7-3a,6:7,11b-di-epoxy-dibenzo[,]isoquinolin-2-ium tri-fluoro-methane-sulfonate.

作者信息

Atioğlu Zeliha, Akkurt Mehmet, Mammadova Gunay Z, Mlowe Sixberth

机构信息

Department of Aircraft Electrics and Electronics, School of Applied Sciences, Cappadocia University, Mustafapaşa, 50420 Ürgüp, Nevşehir, Turkey.

Department of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, Turkey.

出版信息

Acta Crystallogr E Crystallogr Commun. 2021 Oct 8;77(Pt 11):1072-1077. doi: 10.1107/S2056989021010173. eCollection 2021 Nov 1.

In the cation of the title salt, CHNO ·CFOS, the four tetra-hydro-furan rings adopt envelope conformations. In the crystal, pairs of cations are linked by dimeric C-H⋯O hydrogen bonds, forming two (6) ring motifs parallel to the (001) plane. The cations and anions are connected by further C-H⋯O hydrogen bonds, forming a three-dimensional network structure. Hirshfeld surface analysis indicates that the most important contributions to the crystal packing are from H⋯H (47.6%), C⋯H/H⋯C (20.6%), O⋯H/H⋯O (18.0%) and F⋯H/H⋯F (9.9%) inter-actions.