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六氟磷酸二氰基[三(2-吡啶甲基)胺]钴(III)

Dicyanido[tris-(2-pyridyl-meth-yl)amine]-cobalt(III) hexa-fluorido-phosphate.

作者信息

Yu Fan, Li Bao

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m566. doi: 10.1107/S1600536811012001. Epub 2011 Apr 13.

DOI:10.1107/S1600536811012001
PMID:21754296
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3089135/
Abstract

In the title complex, [Co(CN)(2)(C(18)H(18)N(4))]PF(6), the Co(III) atom together with one of the pyridyl rings and two cyanide anions are located on a mirror plane, while the P atom is located on an inversion centre. The Co(III) atom exhibits an octa-hedral geometry, coordinated by four N atoms from the tris-(2-pyridyl-meth-yl)amine ligand with an average Co-N distance of 1.953 (2) Å, and two cyanide C atoms with an average Co-C distance of 1.895 (2) Å. The crystal packing is stabilized by inter-molecular C-H⋯N and C-H⋯F inter-actions.

摘要

在标题配合物[Co(CN)₂(C₁₈H₁₈N₄)]PF₆中,Co(III)原子与其中一个吡啶环和两个氰根阴离子位于一个镜面平面上,而P原子位于一个对称中心上。Co(III)原子呈现八面体几何构型,由三(2 - 吡啶基甲基)胺配体的四个N原子配位,平均Co - N距离为1.953(2) Å,以及两个氰根C原子配位,平均Co - C距离为1.895(2) Å。晶体堆积通过分子间C - H⋯N和C - H⋯F相互作用得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e0bf/3089135/7d03d4261ab5/e-67-0m566-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e0bf/3089135/32dd79cbf504/e-67-0m566-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e0bf/3089135/7d03d4261ab5/e-67-0m566-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e0bf/3089135/32dd79cbf504/e-67-0m566-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e0bf/3089135/7d03d4261ab5/e-67-0m566-fig2.jpg

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