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[3,3'-双(1-萘基甲基)-1,1'-(2,2'-氧二亚乙基)双-(咪唑-2-亚基)]汞(II)双(六氟磷酸根)乙腈溶剂合物

[3,3'-Bis(1-naphthylmethyl)-1,1'-(2,2'-oxy-diethyl-ene)bis-(imidazol-2-yl-idene)]mercury(II) bis-(hexa-fluorido-phosphate) acetonitrile solvate.

作者信息

Guo Wen-Yan, Dong Gui-Ying

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 23;65(Pt 2):m217. doi: 10.1107/S1600536809001743.

DOI:10.1107/S1600536809001743
PMID:21581810
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968318/
Abstract

In the title compound, Hg(C(32)H(30)N(4)O)(2)·CH(3)CN, the mercury(II) ion is coordinated by two carbene C atoms [Hg-C = 2.060 (6) and 2.066 (6) Å] and one ether O atom [Hg-O = 2.561 (5) Å] in a distorted T-shaped geometry with a C-Hg-C angle of 166.3 (3)°. One hexa-fluorido-phosphate anion is rotationally disordered between two orientations with an approximate ratio of 2:1. The crystal packing exhibits weak inter-molecular C-H⋯F and C-H⋯N inter-actions.

摘要

在标题化合物Hg(C₃₂H₃₀N₄O)₂·CH₃CN中，汞(II)离子由两个卡宾C原子[Hg-C = 2.060 (6) 和2.066 (6) Å]和一个醚O原子[Hg-O = 2.561 (5) Å]配位，形成扭曲的T形几何构型，C-Hg-C角为166.3 (3)°。一个六氟磷酸根阴离子在两个取向之间旋转无序，近似比例为2:1。晶体堆积表现出弱的分子间C-H⋯F和C-H⋯N相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2a57/2968318/dde6209557e3/e-65-0m217-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2a57/2968318/dde6209557e3/e-65-0m217-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2a57/2968318/dde6209557e3/e-65-0m217-fig1.jpg

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引用本文的文献

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