二氯{N-[2-(二苯基膦基)亚苄基]异丙胺-κN,P}钯(II) 二甲亚砜单溶剂合物
Dichlorido{N-[2-(diphenyl-phosphan-yl)benzyl-idene]isopropyl-amine-κN,P}palladium(II) dimethyl sulfoxide monosolvate.
作者信息
Chiririwa Haleden, Meijboom Reinout, Omondi Bernard
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m608-9. doi: 10.1107/S1600536811013936. Epub 2011 Apr 16.
Abstract
In the title Pd(II) complex, [PdCl(2)(C(22)H(22)NP)]·(CH(3))(2)SO, the Pd(II) atom is coordinated in an NPCl(2) coordination sphere by the N(imino) and P(phosphane) atoms of the ligand and by two Cl(-) ions in a slightly distorted square-planar geometry [r.m.s. deviation = 0.081 (3) Å, plane defined by the four atoms around the Pd atom]. The dimethyl sulfoxide solvent mol-ecules form centrosymmetric dimers due to an inter-molecular C-H⋯O inter-action. The crystal structure is further stabilized through two inter-molecular C-H⋯π inter-actions.
摘要
在标题化合物二价钯配合物[PdCl₂(C₂₂H₂₂NP)]·(CH₃)₂SO中，二价钯原子通过配体的N（亚氨基）和P（膦）原子以及两个Cl⁻离子在NPCl₂配位球中配位，呈轻微扭曲的平面正方形几何构型[r.m.s.偏差 = 0.081 (3) Å，由钯原子周围的四个原子定义平面]。由于分子间C—H⋯O相互作用，二甲基亚砜溶剂分子形成中心对称二聚体。晶体结构通过两个分子间C—H⋯π相互作用进一步稳定。
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