顺式二氯[2-(3,5-二甲基-1H-吡唑-1-基-κN(2))乙胺-κN]钯(II)二氯甲烷单溶剂合物
cis-Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN(2))ethanamine-κN]palladium(II) dichloro-methane monosolvate.
作者信息
Obuah Collins, Darkwa James, Muller Alfred
机构信息
Department of Chemistry, University of Johannesburg (APK Campus), PO Box 524, Auckland Park, Johannesburg, 2006, South Africa.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):m1103. doi: 10.1107/S1600536812032308. Epub 2012 Jul 21.
In the title compound, [PdCl(2)(C(7)H(13)N(3))]·CH(2)Cl(2), the 2-(3,5-dimethyl-1H-pyrazol-1-yl)ethanamine ligand chelates the Pd(II) atom via two N atoms forming a six-membered ring resulting in a distorted square-planar metal coordination environment, highlighted by N-Pd-Cl angles of 172.63 (8) and 174.98 (9)°. In addition to N-H⋯Cl hydrogen bonds creating infinite chains along [001], several C-H⋯Cl inter-actions are observed in the crystal structure.
在标题化合物[PdCl₂(C₇H₁₃N₃)]·CH₂Cl₂中，2-(3,5-二甲基-1H-吡唑-1-基)乙胺配体通过两个氮原子与Pd(II)原子螯合，形成一个六元环，导致金属配位环境呈扭曲的平面正方形，其特征是N-Pd-Cl角为172.63 (8)°和174.98 (9)°。除了形成沿[001]方向的无限链的N-H⋯Cl氢键外，在晶体结构中还观察到若干C-H⋯Cl相互作用。
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