Obuah Collins, Darkwa James, Muller Alfred
Department of Chemistry, University of Johannesburg (APK Campus), PO Box 524, Auckland Park, Johannesburg, 2006, South Africa.
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):m1103. doi: 10.1107/S1600536812032308. Epub 2012 Jul 21.
In the title compound, [PdCl(2)(C(7)H(13)N(3))]·CH(2)Cl(2), the 2-(3,5-dimethyl-1H-pyrazol-1-yl)ethanamine ligand chelates the Pd(II) atom via two N atoms forming a six-membered ring resulting in a distorted square-planar metal coordination environment, highlighted by N-Pd-Cl angles of 172.63 (8) and 174.98 (9)°. In addition to N-H⋯Cl hydrogen bonds creating infinite chains along [001], several C-H⋯Cl inter-actions are observed in the crystal structure.
在标题化合物[PdCl₂(C₇H₁₃N₃)]·CH₂Cl₂中，2-(3,5-二甲基-1H-吡唑-1-基)乙胺配体通过两个氮原子与Pd(II)原子螯合，形成一个六元环，导致金属配位环境呈扭曲的平面正方形，其特征是N-Pd-Cl角为172.63 (8)°和174.98 (9)°。除了形成沿[001]方向的无限链的N-H⋯Cl氢键外，在晶体结构中还观察到若干C-H⋯Cl相互作用。
