（苄基苯基亚砜-κO）二氯二苯基锡（IV）
(Benzyl phenyl sulfoxide-κO)dichloridodiphenyl-tin(IV).
作者信息
Tan Guo-Xia, Zhang Chang-Fa, Liu Xi-Cheng
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m632. doi: 10.1107/S1600536811014474. Epub 2011 Apr 29.
Abstract
The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)Cl(2)(C(13)H(12)OS)], displays a distorted C(2)Cl(2)O trigonal-bipyramidal coordination environment, with a mean Sn-C distance of 2.121 (9) Å and with Sn-O = 2.331 (2) Å. The Sn(IV) atom is displaced by 0.169 (2) Å from the equatorial C(2)Cl plane towards the direction of the second axially bonded Cl atom.
摘要
在标题化合物[Sn(C₆H₅)₂Cl₂(C₁₃H₁₂OS)]中，Sn(IV)原子呈现出扭曲的C₂Cl₂O三角双锥配位环境，平均Sn-C键长为2.121 (9) Å，Sn-O键长为2.331 (2) Å。Sn(IV)原子从赤道面C₂Cl平面朝着第二个轴向键合的Cl原子方向位移了0.169 (2) Å。
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