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链状聚[[[[2-(2-吡啶基-κN)-1H-苯并咪唑-κN]铜(II)]-μ-L-蛋氨酸根合-κN,O:O']高氯酸盐]

catena-Poly[[[[2-(2-pyridyl-κN)-1H-benzimidazole-κN]copper(II)]-μ-l-methio-ninato-κN,O:O'] perchlorate].

作者信息

Lu Yan-Mei, Le Xue-Yi

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m642-3. doi: 10.1107/S1600536811014000. Epub 2011 Apr 29.

DOI:10.1107/S1600536811014000
PMID:21754350
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3089275/
Abstract

The structure of the title compound, {[Cu(C(5)H(10)NO(2)S)(C(12)H(9)N(3))]ClO(4)}(n), has ortho-rhom-bic symmetry. The chain structure is constructed from square-pyramidally coordinated Cu(II) atoms linked through l-methio-nate ligands. The chains propagate along the a-axis direction and are linked to perchlorate anions via N-H⋯O hydrogen bonds.

摘要

标题化合物{[Cu(C₅H₁₀NO₂S)(C₁₂H₉N₃)]ClO₄}ₙ的结构具有正交晶系对称性。链状结构由通过L-甲硫氨酸配体连接的四方锥配位的Cu(II)原子构成。这些链沿着a轴方向延伸，并通过N-H⋯O氢键与高氯酸根阴离子相连。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fab9/3089275/79687e003ea6/e-67-0m642-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fab9/3089275/5f07e7048b45/e-67-0m642-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fab9/3089275/79687e003ea6/e-67-0m642-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fab9/3089275/5f07e7048b45/e-67-0m642-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fab9/3089275/79687e003ea6/e-67-0m642-fig2.jpg

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Synthesis, X-ray crystal structures and biomimetic and anticancer activities of novel copper(II)benzoate complexes incorporating 2-(4'-thiazolyl)benzimidazole (thiabendazole), 2-(2-pyridyl)benzimidazole and 1,10-phenanthroline as chelating nitrogen donor ligands.新型苯甲酸铜（II）配合物的合成、X射线晶体结构以及仿生和抗癌活性，该配合物包含2-（4'-噻唑基）苯并咪唑（噻苯达唑）、2-（2-吡啶基）苯并咪唑和1,10-菲咯啉作为螯合氮供体配体。
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铜（II）-2-（2-吡啶基）-苯并咪唑与脂肪族或芳香族二羧酸的混合配体配合物：合成、表征及生物活性
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Synthesis, antimicrobial activity and chemotherapeutic potential of inorganic derivatives of 2-(4'-thiazolyl)benzimidazole[thiabendazole]: X-ray crystal structures of [Cu(TBZH)2Cl]Cl.H2O.EtOH and TBZH2NO3 (TBZH=thiabendazole).2-(4'-噻唑基)苯并咪唑[噻苯达唑]无机衍生物的合成、抗菌活性及化疗潜力：[Cu(TBZH)2Cl]Cl.H2O.EtOH和TBZH2NO3（TBZH = 噻苯达唑）的X射线晶体结构
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