链状聚[[[[2-(2-吡啶基-κN)-1H-苯并咪唑-κN]铜(II)]-μ-L-蛋氨酸根合-κN,O:O']高氯酸盐]
catena-Poly[[[[2-(2-pyridyl-κN)-1H-benzimidazole-κN]copper(II)]-μ-l-methio-ninato-κN,O:O'] perchlorate].
作者信息
Lu Yan-Mei, Le Xue-Yi
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m642-3. doi: 10.1107/S1600536811014000. Epub 2011 Apr 29.
Abstract
The structure of the title compound, {[Cu(C(5)H(10)NO(2)S)(C(12)H(9)N(3))]ClO(4)}(n), has ortho-rhom-bic symmetry. The chain structure is constructed from square-pyramidally coordinated Cu(II) atoms linked through l-methio-nate ligands. The chains propagate along the a-axis direction and are linked to perchlorate anions via N-H⋯O hydrogen bonds.
摘要
标题化合物{[Cu(C₅H₁₀NO₂S)(C₁₂H₉N₃)]ClO₄}ₙ的结构具有正交晶系对称性。链状结构由通过L-甲硫氨酸配体连接的四方锥配位的Cu(II)原子构成。这些链沿着a轴方向延伸，并通过N-H⋯O氢键与高氯酸根阴离子相连。
Zotero 插件