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(3R,4S)-3,4-Isopropylidenedioxy-5-phenylsulfonylmethyl-3,4-dihydro-2H-pyrrole 1-oxide.

作者信息

Flores Mari Fe, Garcia P, M Garrido Narciso, Sanz Francisca, Diez David

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):o1115. doi: 10.1107/S1600536811010737. Epub 2011 Apr 13.

DOI:10.1107/S1600536811010737
PMID:21754431
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3089343/
Abstract

The title compound, C(14)H(17)NO(5)S, was prepared by oxidation of (2R,3S,4R)-2-phenyl-sulfonyl-methyl-1-hy-droxy-3,4-iso-pro-pyl-idene-dioxy-pyrrolidine. Its crystal structure confirms unequivocally its configuration. Two inter-molecular C-H⋯O inter-actions help to establish the packing.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8249/3089343/59a8bbcb4a55/e-67-o1115-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8249/3089343/da91868e9245/e-67-o1115-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8249/3089343/796cb9265562/e-67-o1115-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8249/3089343/59a8bbcb4a55/e-67-o1115-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8249/3089343/da91868e9245/e-67-o1115-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8249/3089343/796cb9265562/e-67-o1115-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8249/3089343/59a8bbcb4a55/e-67-o1115-fig3.jpg

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引用本文的文献

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本文引用的文献

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Synthesis of a new chiral pyrrolidine.新型手性吡咯烷的合成。
Molecules. 2010 Mar 9;15(3):1501-12. doi: 10.3390/molecules15031501.
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The advent and development of organocatalysis.有机催化的出现与发展。
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A short history of SHELX.SHELX简史。
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5-Pyrrolidin-2-yltetrazole as an asymmetric organocatalyst for the addition of ketones to nitro-olefins.
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