North Henry, Wutoh Kwame, Odoom M'egya K, Karla Pradeep, Scott Kenneth R, Butcher Ray J
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):o1283-4. doi: 10.1107/S1600536811005678. Epub 2011 Apr 29.
In the title compound, C(14)H(16)ClNO, the dihedral angle between the benzene ring and the conjugated part of the cyclo-hexene ring is 61.7 (2)°. Part of the cyclo-hexene ring and one of the attached methyl groups are disordered over two orientations with occupancies of 0.602 (7) and 0.398 (7). In addition, the crystal studied was a racemic twin [Flack parameter = 0.58 (4)]. In the crystal, the mol-ecules are linked into chains in the b-axis direction by inter-molecular N-H⋯O hydrogen bonds. C-H⋯O and C-H⋯Cl inter-actions are also observed.
在标题化合物C₁₄H₁₆ClNO中，苯环与环己烯环共轭部分之间的二面角为61.7 (2)°。环己烯环的一部分和一个相连的甲基在两种取向上无序，占有率分别为0.602 (7)和0.398 (7)。此外，所研究的晶体是一个外消旋孪晶[弗莱克参数 = 0.58 (4)]。在晶体中，分子通过分子间的N-H⋯O氢键在b轴方向上连接成链。还观察到C-H⋯O和C-H⋯Cl相互作用。
