四氯化双（二苄基亚砜-κO）锡（IV）
Tetra-chloridobis(dibenzyl sulfoxide-κO)tin(IV).
作者信息
Keng Thy Chun, Lo Kong Mun, Ng Seik Weng
机构信息
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m660. doi: 10.1107/S1600536811015704. Epub 2011 May 7.
Abstract
The six-coordinate Sn(IV) atom in the title compound, [SnCl(4)(C(14)H(14)OS)(2)], exists in a cis-SnCl(4)O(2) octa-hedral geometry. Of the four Cl atoms, two are close to adjacent S atoms [Cl⋯S = 3.320 (1) and 3.376 (1) Å]; the Sn-Cl bonds involving these two Cl atoms are longer than the other two Sn-Cl bonds.
摘要
在标题化合物[SnCl₄(C₁₄H₁₄OS)₂]中，六配位的Sn(IV)原子呈顺式SnCl₄O₂八面体几何构型。在四个Cl原子中，有两个靠近相邻的S原子[Cl⋯S = 3.320 (1) 和3.376 (1) Å]；涉及这两个Cl原子的Sn-Cl键比另外两个Sn-Cl键长。
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