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三(2-氯苄基)[3-(4-甲基苯基)-2-烯丙酸根-κO]锡(IV)

Tris(2-chloro-benz-yl)[3-(4-methyl-phen-yl)prop-2-enoato-κO]tin(IV).

作者信息

Keng Thy Chun, Lo Kong Mun, Ng Seik Weng

机构信息

Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m664. doi: 10.1107/S1600536811015741. Epub 2011 May 7.

Abstract

The Sn(IV) atom in the title compound, [Sn(C(7)H(6)Cl)(3)(C(10)H(9)O(2))], exists in a tetra-hedral geometry [Σ C-Sn-C = 341.5 (4)°]. If the doubly bonded carbonyl O atom is taken into account for the coordination sphere of Sn [Sn⋯O = 2.808 (2) Å], the coordination geometry can be described as a cis-penta-gonal bipyramid.

摘要

在标题化合物[Sn(C₇H₆Cl)₃(C₁₀H₉O₂)]中,Sn(IV)原子呈四面体几何构型[Σ C-Sn-C = 341.5 (4)°]。如果将羰基的双键氧原子计入Sn的配位球[Sn⋯O = 2.808 (2) Å],则配位几何构型可描述为顺式五角双锥。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed1e/3120499/4d4551e9668e/e-67-0m664-fig1.jpg

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