Keng Thy Chun, Lo Kong Mun, Ng Seik Weng
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m664. doi: 10.1107/S1600536811015741. Epub 2011 May 7.
The Sn(IV) atom in the title compound, [Sn(C(7)H(6)Cl)(3)(C(10)H(9)O(2))], exists in a tetra-hedral geometry [Σ C-Sn-C = 341.5 (4)°]. If the doubly bonded carbonyl O atom is taken into account for the coordination sphere of Sn [Sn⋯O = 2.808 (2) Å], the coordination geometry can be described as a cis-penta-gonal bipyramid.
在标题化合物[Sn(C₇H₆Cl)₃(C₁₀H₉O₂)]中,Sn(IV)原子呈四面体几何构型[Σ C-Sn-C = 341.5 (4)°]。如果将羰基的双键氧原子计入Sn的配位球[Sn⋯O = 2.808 (2) Å],则配位几何构型可描述为顺式五角双锥。