Liu Xi-Cheng, Jiang Wen-Tao, Shan Peng-Cheng, Ding Wen-Chao
Department of Chemistry, Qufu Normal University, Qufu 273165, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m883. doi: 10.1107/S1600536811020496. Epub 2011 Jun 11.
In the title compound, [Sn(C(6)H(11))(3)(C(7)H(3)Br(2)O(3))], the Sn atom is four-coordinate and possesses a distorted Sn(C(3)O) tetra-hedral geometry, with Sn-C bond lengths in the range 2.132 (6)-2.144 (6) Å and with Sn-O = 2.086 (4) Å. The uncoordinated carboxyl-ate O atom forms a weak contact with the Sn atom, with an Sn⋯O separation of 2.962 (2) Å.
在标题化合物[Sn(C₆H₁₁)₃(C₇H₃Br₂O₃)]中,Sn原子为四配位,具有扭曲的Sn(C₃O)四面体几何构型,Sn—C键长在2.132 (6) - 2.144 (6) Å范围内,Sn—O键长为2.086 (4) Å。未配位的羧酸根O原子与Sn原子形成弱相互作用,Sn⋯O间距为2.962 (2) Å。