Daly Christopher G, Singh Kuldip, Cross Warren B
Department of Chemistry, University of Leicester, University Road, Leicester LE1 7RH, England.
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m668. doi: 10.1107/S1600536811015431. Epub 2011 May 7.
In the title complex, [PdI(2)(C(24)H(31)N(3))(2)]·2C(6)H(6), the Pd(2+) ion is located on an inversion centre in a slightly distorted square-planar geometry. The angle between the I(2)C(2) square plane and the mean plane of the N-heterocyclic carbene ring is 79.8 (2)°, with I-Pd-C-N torsion angles of -81.1 (6) and -78.2 (5)°. The Pd-carbene and Pd-I distances are 2.016 (6) and 2.5971 (10) Å, respectively.
在标题配合物[PdI₂(C₂₄H₃₁N₃)₂]·2C₆H₆中，Pd²⁺离子位于一个反演中心上，呈略微扭曲的平面正方形几何构型。I₂C₂平面与N-杂环卡宾环的平均平面之间的夹角为79.8 (2)°，I-Pd-C-N扭转角为-81.1 (6)°和-78.2 (5)°。Pd-卡宾和Pd-I的距离分别为2.016 (6) Å和2.5971 (10) Å。
