Duong Adam, Wuest James D, Maris Thierry
Département de Chimie, Université de Montréal, 2900 Boulevard Edouard-Montpetit, Montréal, Québec, Canada H3C 3J7.
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m518. doi: 10.1107/S1600536811010713. Epub 2011 Apr 7.
In the title compound, [PdCl(2)(C(5)H(6)BNO(2))(2)]·2C(2)H(6)OS, the Pd(II) ion is located on an inversion centre and is four-coordinated in a trans square-planar geometry by two chloride ions and two (pyridin-4-yl)boronic acid ligands. The Pd-N and Pd-Cl distances are 2.023 (2) and 2.2977 (7) Å, respectively, and the average N-Pd-Cl angle is 90°. The dimethyl sulfoxide solvent mol-ecules play a key role in the crystal structure by bridging the complex mol-ecules via O-H⋯O hydrogen bonds, forming tapes running along the b axis. C-H⋯O inter-actions also contribute to the cohesion of the crystal.
在标题化合物[PdCl₂(C₅H₆BNO₂)₂]·2C₂H₆OS中,Pd(II)离子位于一个对称中心上,通过两个氯离子和两个(吡啶-4-基)硼酸配体以反式平面正方形几何构型进行四配位。Pd-N和Pd-Cl的距离分别为2.023(2) Å和2.2977(7) Å,平均N-Pd-Cl角为90°。二甲基亚砜溶剂分子通过O-H⋯O氢键桥连配合物分子,在晶体结构中起关键作用,形成沿b轴延伸的链状结构。C-H⋯O相互作用也有助于晶体的凝聚。