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链状聚[[双-(硝酸根-κO)铜(II)]-双-[μ-1,4-双-(吡啶-3-基甲氧基)苯-κN:N']]

catena-Poly[[bis-(nitrato-κO)copper(II)]-bis-[μ-1,4-bis-(pyridin-3-ylmeth-oxy)benzene-κN:N']].

作者信息

Zou Ping, Liu Ying, Hou Guang-Feng, Gao Jin-Sheng

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m692. doi: 10.1107/S1600536811016096. Epub 2011 May 7.

DOI:10.1107/S1600536811016096
PMID:21754597
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3120522/
Abstract

In the title compound, Cu(NO(3))(2)(C(18)H(16)N(2)O(2))(2), the Cu(II) ion lies on an inversion center and is six-coordinated in a Jahn-Teller-distored octa-hedral geometry defined by four N atoms of the pyridine derivative forming a square plane, above and below which are the O atoms of the nitrate anion. The ligand links the metal atoms linto a linear chain running along the a axis. One of the nitrate O atoms is equally disordered over two sets of sites.

摘要

在标题化合物[Cu(NO₃)₂(C₁₈H₁₆N₂O₂)₂]ₙ中,Cu(II)离子位于一个对称中心上,呈六配位,具有 Jahn-Teller 畸变的八面体几何构型,由吡啶衍生物的四个 N 原子形成一个正方形平面,硝酸根阴离子的 O 原子在该平面的上方和下方。配体将金属原子连接成沿 a 轴延伸的线性链。其中一个硝酸根的 O 原子在两组位置上无序分布。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b0a/3120522/3eef1ccbb290/e-67-0m692-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b0a/3120522/dcf5fc34199b/e-67-0m692-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b0a/3120522/3eef1ccbb290/e-67-0m692-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b0a/3120522/dcf5fc34199b/e-67-0m692-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b0a/3120522/3eef1ccbb290/e-67-0m692-fig2.jpg

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引用本文的文献

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本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
catena-Poly[[bis-(nitrato-κO)cobalt(II)]-bis-[μ-1,4-bis-(pyridin-3-ylmeth-oxy)benzene-κN:N']].
链状聚[[双-(硝酸根-κO)钴(II)]-双-[μ-1,4-双-(吡啶-3-基甲氧基)苯-κN:N']]
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m789. doi: 10.1107/S1600536811018630. Epub 2011 May 25.